基本解释：1，3-二亚氨基异吲哚
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To find highly efficient photocatalysis materials,complex iron(Ⅱ) 1,4-dithiin-diphenyl porphyrazine(FePzPh(dtn)4) and its sulfonation derivatives(FePzSPh(dtn)4) were synthesized from 2,3-dithiolate-1,4-dithiin and 1,3-diiminoisoindoline by solid-state method using ammonium molybdate as a catalyst in the presence of ferrous sulfate heptahydrate.为寻求更高效的光催化剂,以1,3-二亚氨基异吲哚啉和2,3-二氰基-1,4-二噻英为原料,钼酸铵为催化剂,七水合硫酸亚铁为模板,用固相法合成了二(1,4-二噻英)-二苯基四氮杂卟啉铁(FePzPh(dtn)4),并对其进行了磺化改性(FePzSPh(dtn)4)。
To improve the solubility properties and find highly efficient photocatalysis materials,the assymmetric iron(Ⅱ) 1,4-dithiin-diphenyl porphyrazine FePcPz(dtn)4 and its chloridized,FePcClPz(dtn)4 were synthesized from 2,3-dithiolate-1,4-dithiin and 1,3-diiminoisoindoline by solid-state method.为改善催化剂的溶解性能,以寻求更高效的光催化剂,以1,3-二亚氨基异吲哚啉和2,3-二氰基-1,4-二噻英为原料,用固相法合成了不对称型1,4-二噻英-二苯基四氮杂卟啉铁FePcPz(dtn)4及其氯代改性FePcClPz(dtn)4。
Then 1,3-diiminoisoindolium nitrate was neutralized with sodium hydroxide to afford 1,3-diiminoisoindoline.以硬脂酸和油酸为乳化剂、钼酸铵为催化剂,尿素和邻苯二甲酸酐经亚氨化,然后在硝酸铵存在下发生缩合反应得到1,3-双亚氨基异吲哚啉的硝酸盐,最后用氢氧化钠中和得到1,3-双亚氨基异吲哚啉。
